Researchers Find New Way to Bond Composite Layers

Researchers have found a way to bond composite layers, producing a material that is substantially stronger and more resistant to damage than other advanced composites.

The latest Airbus and Boeing passenger jets flying today are made primarily from advanced composite materials such as carbon fibre reinforced plastic — extremely lightweight, durable materials that reduce the overall weight of the plane by as much as 20% compared to aluminium-bodied planes. Such lightweight airframes translate directly to fuel savings, which is a major point in advanced composites’ favour.

But composite materials are also surprisingly vulnerable: While aluminium can withstand relatively large impacts before cracking, the many layers in composites can break apart due to relatively small impacts — a drawback that is considered the material’s Achilles’ heel.

MIT aerospace engineers have found a way to bond composite layers in such a way that the resulting material is substantially stronger and more resistant to damage than other advanced composites.

The researchers fastened the layers of composite materials together using carbon nanotubes — atom-thin rolls of carbon that, despite their microscopic stature, are incredibly strong. They embedded tiny “forests” of carbon nanotubes within a glue-like polymer matrix, then pressed the matrix between layers of carbon fibre composites. The nanotubes, resembling tiny, vertically aligned stitches, worked themselves within the crevices of each composite layer, serving as a scaffold to hold the layers together.

MIT-Stitched-Composites-2

In experiments to test the material’s strength, the team found that, compared with existing composite materials, the stitched composites were 30% stronger, withstanding greater forces before breaking apart.

Roberto Guzman, who led the work as an MIT postdoc in the Department of Aeronautics and Astronautics (AeroAstro), says the improvement may lead to stronger, lighter airplane parts — particularly those that require nails or bolts, which can crack conventional composites.

More work needs to be done, but we are really positive that this will lead to stronger, lighter planes. That means a lot of fuel saved, which is great for the environment and for our pockets.

Today’s composite materials are composed of layers, or plies, of horizontal carbon fibres, held together by a polymer glue, which Wardle describes as “a very, very weak, problematic area.” Attempts to strengthen this glue region include Z-pinning and 3-D weaving — methods that involve pinning or weaving bundles of carbon fibres through composite layers, similar to pushing nails through plywood, or thread through fabric.

A stitch or nail is thousands of times bigger than carbon fibres. So when you drive them through the composite, you break thousands of carbon fibres and damage the composite.

Carbon nanotubes, by contrast, are about 10 nanometers in diameter — nearly a million times smaller than the carbon fibres. Researchers we’re able to put these nanotubes in without disturbing the larger carbon fibres, and that’s what maintains the composite’s strength.

Guzman and Wardle came up with a technique to integrate a scaffold of carbon nanotubes within the polymer glue. They first grew a forest of vertically aligned carbon nanotubes, following a procedure that Wardle’s group previously developed. They then transferred the forest onto a sticky, uncured composite layer and repeated the process to generate a stack of 16 composite plies — a typical composite laminate makeup — with carbon nanotubes glued between each layer.

To test the material’s strength, the team performed a tension-bearing test — a standard test used to size aerospace parts — where the researchers put a bolt through a hole in the composite, then ripped it out. While existing composites typically break under such tension, the team found the stitched composites were stronger, able to withstand 30 percent more force before cracking.

The researchers also performed an open-hole compression test, applying force to squeeze the bolt hole shut. In that case, the stitched composite withstood 14 percent more force before breaking, compared to existing composites.

The strength enhancements suggest this material will be more resistant to any type of damaging events or features. And since the majority of the newest planes are more than 50% composite by weight, improving these state-of-the art composites has very positive implications for aircraft structural performance.

This work was supported by Airbus Group, Boeing, Embraer, Lockheed Martin, Saab AB, Spirit AeroSystems Inc., Textron Systems, ANSYS, Hexcel, and TohoTenax through MIT’s Nano-Engineered Composite aerospace STructures (NECST) Consortium and, in part, by the U.S. Army.

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